Image & Video Credit & Copyright: NASA & Roscosmos.
May 23, 2011; As Soyuz TMA-20 undocked from the ISS to return the crew of Expedition 27 home to Earth they captured for the first time, a Space Shuttle (STS-134 Endeavour) while docked to the ISS. The three crewmembers; cosmonaut Dmitry Kondratyev, NASA astronaut Cady Coleman and ESA astronaut Paolo Nespoli backed away from ISS; Nespoli filmed the view for record.
NASA STS-134 Mission Gallery: http://spaceflight.nasa.gov/gallery/images/shuttle/sts-134/ndxpage11.html